|
|Section2= |Section3= |Section7= |Section8= }} Hydrogen selenide is an inorganic compound with the formula H2Se. It is the simplest (and virtually the only) hydride of selenium. H2Se is a colorless, flammable gas under standard conditions. It is the most toxic selenium compound〔http://www.epa.gov/ttnatw01/hlthef/selenium.html, US Environmental Protection Agency, Air Toxins website〕 with an exposure limit of 0.05 ppm over an 8 hour period.〔http://www.cdc.gov/niosh/idlh/7783075.html, Documentation of Immediately Dangerous to Life or Health Concentrations: Hydrogen Selenide, The National Institute for Occupational Safety and Health〕〔http://www.cdc.gov/niosh/docs/81-123/pdfs/0336.pdf Occupational Health Guideline for Hydrogen Selenide, The National Institute for Occupational Safety and Health, 1978〕 Even at extremely low concentrations, this compound has a very irritating smell resembling that of decayed horseradish or 'leaking gas', but smells of rotten eggs at higher concentrations. ==Structure and properties== H2Se adopts a "bent" structure with a H-Se-H bond angle of 91°. Consistent with this structure, three IR-active vibrational bands are observed: 2358, 2345, and 1034 cm−1. The properties of H2S and H2Se are similar, although the selenide is more acidic with p''K''a = 3.89, and the second p''K''a = 11.0 at 25 °C. Reflecting its acidity, H2Se is soluble in water. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「hydrogen selenide」の詳細全文を読む スポンサード リンク
|